Safety
Calcium hypochlorite is stored dry and cold, away from any acid, organic materials, and metals. The hydrated form is safer to handle.
If mixed with an acid it releases highly toxic chlorine gas.
A confusion sometimes reigns between calcium oxychlorides and calcium hypochlorite. Indeed, the name calcium oxychloride (or calcium hydroxychloride) does not immediately refer to calcium hypochlorite, but is only applicable to the mixed calcium basic chloride compounds remaining unreacted in the bleaching powder, such as, e.g. CaCl2 · 2 Ca(OH)2.
Calcium oxychloride may also be formed in concrete in roads and bridges when calcium chloride is used as deicing agent during winter. Calcium chloride then reacts with calcium hydroxide (portlandite) present in cement hydration products and forms a deleterious expanding phase also named CAOXY (abbreviation for calcium oxychloride) by concrete technologists. The stress induced into concrete by crystallisation pressure and CAOXY salt expansion can considerably reduce the strength of concrete.
Calcium hypochlorite exhibits both acido-basic and oxydo-reduction properties. It is a relatively strong base.
Calcium hypochlorite solution is basic as the hypochlorite anion can accept a proton from a water molecule leaving a hydroxyُl anion in solution. This basicity is due to the propensity for the hypochlorite anion to accept a proton to become hypochlorous acid, a weak acid:
The hypochlorite anion is also a strong oxidizing agent containing a chlorine atom at the valence I (redox state: Cl+1) which reacts under acidic conditions with the reduced chloride species (Cl–, here the reducing agent) present in hydrochloric acid to form calcium chloride, water and gaseous chlorine. The overall reaction is:
Calcium hypochlorite is stored dry and cold, away from any acid, organic materials, and metals. The hydrated form is safer to handle.
If mixed with an acid it releases highly toxic chlorine gas.
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Inhibitor of salt sedimentations Antiskalant Vitek 3000 allows
to prevent formation of a deposit of slightly soluble inorganic compounds on a surface of membranes in systems of water treatment.
Antiskalant of the Vitec 3000 Brand for the membrane Filmtec elements of the Dow company.
Antiskalant of the ROPUR RPI-3000A Brand for the membrane TORAY elements.
The Antiskalant (antiskalyant, inhibitor of deposits) is intended for prevention of adjournment of a deposit which is formed by insoluble compounds of iron in water, carbonates of shchelochnozemelny and some other metals, on a surface of membranes water purification installations. This reagent is recommended for protection of polyamide membranes.
Application of an antiskalant in practice consists in exact dispensing of reagent in the initial water arriving on installation of the return osmosis (nanofiltration).
Our company at design and production of membrane installations uses two types of inhibitors of salt sedimentations (Antiskalantov) of the membrane elements recommended by producers.
Bleach is the generic name for any chemical product which is used industrially and domestically to remove color from a fabric or fiber or to clean or to remove stains in a process called bleaching. It often refers, specifically, to a dilute solution of sodium hypochlorite, also called "liquid bleach".
Many bleaches have broad spectrum bactericidal properties, making them useful for disinfecting and sterilizing and are used in swimming pool sanitation to control bacteria, viruses, and algae and in many places where sterile conditions are required. They are also used in many industrial processes, notably in the bleaching of wood pulp. Bleaches also have other minor uses like removing mildew, killing weeds, and increasing the longevity of cut flowers.
Bleaches work by reacting with many colored organic compounds, such as natural pigments, and turning them into colorless ones. While most bleaches are oxidizing agents (chemicals that can remove electrons from other molecules), some are reducing agents (that donate electrons).
Chlorine, a powerful oxidizer, is the active agent in many household bleaches. Since pure chlorine is a toxic corrosive gas, these products usually contain hypochlorite which releases chlorine when needed. "Bleaching powder" usually means a formulation containing calcium hypochlorite.
A confusion sometimes reigns between calcium oxychlorides and calcium hypochlorite. Indeed, the name calcium oxychloride (or calcium hydroxychloride) does not immediately refer to calcium hypochlorite, but is only applicable to the mixed calcium basic chloride compounds remaining unreacted in the bleaching powder, such as, e.g. CaCl2 · 2 Ca(OH)2.
Calcium oxychloride may also be formed in concrete in roads and bridges when calcium chloride is used as deicing agent during winter. Calcium chloride then reacts with calcium hydroxide (portlandite) present in cement hydration products and forms a deleterious expanding phase also named CAOXY (abbreviation for calcium oxychloride) by concrete technologists. The stress induced into concrete by crystallisation pressure and CAOXY salt expansion can considerably reduce the strength of concrete.
Calcium hypochlorite exhibits both acido-basic and oxydo-reduction properties. It is a relatively strong base.
Calcium hypochlorite solution is basic as the hypochlorite anion can accept a proton from a water molecule leaving a hydroxyُl anion in solution. This basicity is due to the propensity for the hypochlorite anion to accept a proton to become hypochlorous acid, a weak acid:
The hypochlorite anion is also a strong oxidizing agent containing a chlorine atom at the valence I (redox state: Cl+1) which reacts under acidic conditions with the reduced chloride species (Cl–, here the reducing agent) present in hydrochloric acid to form calcium chloride, water and gaseous chlorine. The overall reaction is:
Calcium hypochlorite is an inorganic compound with formula Ca(ClO)2. It is the main active ingredient of commercial products called bleaching powder, chlorine powder, or chlorinated lime, used for water treatment and as a bleaching agent. This compound is relatively stable and has greater available chlorine than sodium hypochlorite (liquid bleach). It is a white solid, although commercial samples appear yellow. It strongly smells of chlorine, owing to its slow decomposition in moist air. It is not highly soluble in hard water, and is more preferably used in soft to medium-hard water. It has two forms: dry (anhydrous); and hydrated (hydrous).
Calcium hypochlorite is commonly used to sanitize public swimming pools and disinfect drinking water. Generally the commercial substances are sold with a purity of 65% to 73% with other chemicals present, such as calcium chloride and calcium carbonate, resulting from the manufacturing process. As a swimming pool chemical, it is blended with other chemicals less often than other forms of chlorine, due to dangerous reactions with some common pool chemicals. In solution, calcium hypochlorite could be used as a general purpose sanitizer, but due to calcium residue, sodium hypochlorite (bleach) is usually preferred.
Dishwashing liquid (BrE: washing-up liquid), known as dishwashing soap, dish detergent and dish soap, is a detergent used to assist in dishwashing. It is usually a highly-foaming mixture of surfactants with low skin irritation, and is primarily used for hand washing of glasses, plates, cutlery, and cooking utensils in a sink or bowl. In addition to its primary use, dishwashing liquid also has various informal applications, such as for creating bubbles, clothes washing and cleaning oil-affected birds.
Dishwashing detergents for dishwashers are manufactured and marketed variously as cartridges, gel, liquids, pacs, powder, and tablets. Any dishwashing liquid may contain bleach, enzymes, or rinsing aids. Some dishwashing detergents may be homemade, using ingredients such as borax, essential oil, eucalyptus oil and grated bar soap, among others.
Dishwashing detergents can be formulated to work under different circumstances. In some cases suitably formulated they can be used with cold water or sea water, although they will not generally work as well as those intended for, and used with, hot water.
The immersed hull and fittings of a ship at sea, particularly in coastal waters, are subject to algae, barnacle, mussel, and other shellfish growth that can impair its hydrodynamic performance and adversely affect the service of the immersed fittings.
Fittings such as cooling water intake systems are often protected by impressed current antifouling systems, and immersed hulls today are finished with very effective self-polishing antifouling paints.
The functional principle of these systems is the establishment of an artificially triggered voltage difference between copper anodes and the integrated steel plate cathodes. This causes a minor electrical current to flow from the copper anodes, so that they are dissolved to a certain degree. A control unit makes sure that the anodes add the required minimum amount of copper particles to the sea water, thus ensuring the formation of copper oxide that creates ambient conditions precluding local fouling. A control unit can be connected to the management system of the vessel. Using information from the management system, the impressed current antifouling system can determine the amount of copper that needs to be dissolved to give optimum performance with minimum wastage of the anodes.
Citric acid It occurs naturally in citrus fruits. In biochemistry, it is an intermediate in the citric acid cycle, which occurs in the metabolism of all aerobic organisms.
More than two million tons of citric acid are manufactured every year. It is used widely as an acidifier, as a flavoring and a chelating agent.
A citrate is a derivative of citric acid; that is, the salts, esters, and the polyatomic anion found in solution. An example of the former, a salt is trisodium citrate; an ester is triethyl citrate. When part of a salt
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